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1. FC Union Berlin. Union Berlin. 1. FC Union Berlin · -: . An der Alten Försterei · Fortuna Düsseldorf. Fortuna Düsseldorf · Matchcenter. vorheriger Spieltag. 1, -, FC Bayern München · FCBFC BayernFC Bayern München, 31, 73, 23, 4, 4, , + 2, -, Borussia Dortmund · BVBBorussia DortmundBorussia Dortmund​. Und Augsburg? Die empfangen am Spieltag den Tabellendritten aus Leipzig. F 1: 1.

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The plot of this film started with Nordin standing in the middle of the city Kuala Lumpur as he gazed around him. Starting here, Nordin narrate the history of his life, including being a victim of bullying while in school while acknowledging not have many friends.

Nordin, 28 years old, still single and still not married, worked as a designer software in the company's giant computer software Malaysia, Michealsoft owned by Tan Sri Michael Patrick Teoh , Nordin was with Michaelsoft for three years.

Nordin arrived at the office, and Tan Sri Michael announced that it has taken new people as new staff.

A Mitsubishi Lancer car came and hit the road marker for the disabled. The new person in question is Roy. When Nordin surprised by the presence of Roy, he's out of the meeting and has not had time to leave, Roy called him, as he dubbed it "Boyot".

Nordin remembering past events during the secondary school : In , Roy and sit level 3. Roy Nordin Nordin bullying by trying to insert his head in toilet.

Apparently, it was a dream, Nordin screaming while immersing his head in a sink filled with water and see Mirror.

Roy came, and asked him to prepare a working paper reports to clients. Nordin bridge itself in wall toilets and dream again, he turns into The Incredible Hulk with the rest of his body is blue, while her clothes torn his body as a result of growing up, and he scares Roy.

Meanwhile, Dr. Ika drove his car to go home after buying a chicken to be cooked, suddenly tires punctured his car.

In the playground , Nordin enjoy burgers size and bread john watched by people around him. An Indian man came to help Dr. People also continue to observe the behavior of Nordin who eat alone, she contacted her friends.

Indian man who introduced himself as Ravi Shankar helped Dr. Ika change the tire. Ika put the chicken bought at wholesale market in the back of his car, however, that Indian men are unable to do so, Dr.

Ika no choice, and surprised the chicken out of the bag. The tendency to aggregate is common for organolithium compounds.

The aggregates are held together by delocalized covalent bonds between lithium and the terminal carbon of the butyl chain.

The cluster is a distorted cubane-type cluster with Li and C H 2 R groups at alternating vertices. An equivalent description describes the tetramer as a Li 4 tetrahedron interpenetrated with a tetrahedron [ C H 2 R] 4.

Bonding within the cluster is related to that used to describe diborane, but more complex since eight atoms are involved.

Reflecting its "electron-deficient character," n -butyllithium is highly reactive toward Lewis bases. Due to the large difference between the electronegativities of carbon 2.

The standard preparation for n -BuLi is reaction of 1-bromobutane or 1-chlorobutane with Li metal: [2]. Solvents used for this preparation include benzene , cyclohexane, and diethyl ether.

When BuBr is the precursor, the product is a homogeneous solution, consisting of a mixed cluster containing both LiBr and BuLi, together with a small amount of octane.

Solutions of butyllithium, which are susceptible to degradation by air, are standardized by titration.

A popular weak acid is biphenyl methanol, which gives a deeply colored dilithio derivative at the end point.

Butyllithium is principally valued as an initiator for the anionic polymerization of dienes , such as butadiene. Isoprene can be polymerized stereospecifically in this way.

Also of commercial importance is the use of butyllithium for the production of styrene-butadiene polymers. Even ethylene will insert into BuLi.

Furthermore, in addition to being a strong nucleophile, n-BuLi binds to aprotic Lewis bases, such as ethers and tertiary amines , which partially disaggregate the clusters by binding to the lithium centers.

Its use as a strong base is referred to as metalation. Reactions are typically conducted in tetrahydrofuran and diethyl ether , which are good solvents for the resulting organolithium derivatives see below.

The stability and volatility of the butane resulting from such deprotonation reactions is convenient, but can also be a problem for large-scale reactions because of the volume of a flammable gas produced.

The kinetic basicity of n -BuLi is affected by the solvent or cosolvent. Such additives can also aid in the isolation of the lithiated product, a famous example of which is dilithioferrocene.

Schlosser's base is a superbase produced by treating butyllithium with potassium tert-butoxide. It is kinetically more reactive than butyllithium and is often used to accomplish difficult metalations.

The butoxide anion complexes the lithium and effectively produces butylpotassium, which is more reactive than the corresponding lithium reagent.

An example of the use of n-butyllithium as a base is the addition of an amine to methyl carbonate to form a methyl carbamate , where n-butyllithium serves to deprotonate the amine:.

Butyllithium reacts with some organic bromides and iodides in an exchange reaction to form the corresponding organolithium derivative.

The reaction usually fails with organic chlorides and fluorides:. This reaction is useful for preparation of several types of RLi compounds, particularly aryl lithium and some vinyl lithium reagents.

The utility of this method is significantly limited, however, by the presence in the reaction mixture of n-BuBr or n-BuI, which can react with the RLi reagent formed, and by competing dehydrohalogenation reactions, in which n-BuLi serves as a base:.

These side reaction are significantly less important for RI than for RBr, since the iodine-lithium exchange is several orders of magnitude faster than the bromine-lithium exchange.

For these reasons, aryl, vinyl and primary alkyl iodides are the preferred substrates, and t-BuLi rather than n-BuLi is usually used, since the formed t-BuI is immediately destroyed by the t-BuLi in a dehydrohalogenation reaction thus requiring 2 equiv of t-BuLi.

Alternatively, vinyl lithium reagents can be generated by direct reaction of the vinyl halide e. A related family of reactions are the transmetalations , wherein two organometallic compounds exchange their metals.

Many examples of such reactions involve Li exchange with Sn :. The tin-lithium exchange reactions have one major advantage over the halogen-lithium exchanges for the preparation of organolithium reagents, in that the product tin compounds C 4 H 9 SnMe 3 in the example above are much less reactive towards lithium reagents than are the halide products of the corresponding halogen-lithium exchanges C 4 H 9 Br or C 4 H 9 Cl.

Other metals and metalloids which undergo such exchange reactions are organic compounds of mercury , selenium , and tellurium. Organolithium reagents, including n -BuLi are used in synthesis of specific aldehydes and ketones.

One such synthetic pathway is the reaction of an organolithium reagent with disubstituted amides :.

A Mitsubishi Lancer car came and hit the road marker for the disabled. The new person in question is Roy. When Nordin surprised by the presence of Roy, he's out of the meeting and has not had time to leave, Roy called him, as he dubbed it "Boyot".

Nordin remembering past events during the secondary school : In , Roy and sit level 3. Roy Nordin Nordin bullying by trying to insert his head in toilet.

Apparently, it was a dream, Nordin screaming while immersing his head in a sink filled with water and see Mirror.

Roy came, and asked him to prepare a working paper reports to clients. Nordin bridge itself in wall toilets and dream again, he turns into The Incredible Hulk with the rest of his body is blue, while her clothes torn his body as a result of growing up, and he scares Roy.

Meanwhile, Dr. Ika drove his car to go home after buying a chicken to be cooked, suddenly tires punctured his car.

In the playground , Nordin enjoy burgers size and bread john watched by people around him. An Indian man came to help Dr.

People also continue to observe the behavior of Nordin who eat alone, she contacted her friends. Indian man who introduced himself as Ravi Shankar helped Dr.

Ika change the tire. Ika put the chicken bought at wholesale market in the back of his car, however, that Indian men are unable to do so, Dr.

Ika no choice, and surprised the chicken out of the bag. Jalal, who was contacted by Dr. Ika told him not to call her during work, but Dr.

Ika want Jalal hear the case. Ika find the chicken apart and see the chicken out of the glider playground.

Solvents used for this preparation include benzene , cyclohexane, and diethyl ether. When BuBr is the precursor, the product is a homogeneous solution, consisting of a mixed cluster containing both LiBr and BuLi, together with a small amount of octane.

Solutions of butyllithium, which are susceptible to degradation by air, are standardized by titration. A popular weak acid is biphenyl methanol, which gives a deeply colored dilithio derivative at the end point.

Butyllithium is principally valued as an initiator for the anionic polymerization of dienes , such as butadiene. Isoprene can be polymerized stereospecifically in this way.

Also of commercial importance is the use of butyllithium for the production of styrene-butadiene polymers. Even ethylene will insert into BuLi.

Furthermore, in addition to being a strong nucleophile, n-BuLi binds to aprotic Lewis bases, such as ethers and tertiary amines , which partially disaggregate the clusters by binding to the lithium centers.

Its use as a strong base is referred to as metalation. Reactions are typically conducted in tetrahydrofuran and diethyl ether , which are good solvents for the resulting organolithium derivatives see below.

The stability and volatility of the butane resulting from such deprotonation reactions is convenient, but can also be a problem for large-scale reactions because of the volume of a flammable gas produced.

The kinetic basicity of n -BuLi is affected by the solvent or cosolvent. Such additives can also aid in the isolation of the lithiated product, a famous example of which is dilithioferrocene.

Schlosser's base is a superbase produced by treating butyllithium with potassium tert-butoxide.

It is kinetically more reactive than butyllithium and is often used to accomplish difficult metalations.

The butoxide anion complexes the lithium and effectively produces butylpotassium, which is more reactive than the corresponding lithium reagent.

An example of the use of n-butyllithium as a base is the addition of an amine to methyl carbonate to form a methyl carbamate , where n-butyllithium serves to deprotonate the amine:.

Butyllithium reacts with some organic bromides and iodides in an exchange reaction to form the corresponding organolithium derivative.

The reaction usually fails with organic chlorides and fluorides:. This reaction is useful for preparation of several types of RLi compounds, particularly aryl lithium and some vinyl lithium reagents.

The utility of this method is significantly limited, however, by the presence in the reaction mixture of n-BuBr or n-BuI, which can react with the RLi reagent formed, and by competing dehydrohalogenation reactions, in which n-BuLi serves as a base:.

These side reaction are significantly less important for RI than for RBr, since the iodine-lithium exchange is several orders of magnitude faster than the bromine-lithium exchange.

For these reasons, aryl, vinyl and primary alkyl iodides are the preferred substrates, and t-BuLi rather than n-BuLi is usually used, since the formed t-BuI is immediately destroyed by the t-BuLi in a dehydrohalogenation reaction thus requiring 2 equiv of t-BuLi.

Alternatively, vinyl lithium reagents can be generated by direct reaction of the vinyl halide e. A related family of reactions are the transmetalations , wherein two organometallic compounds exchange their metals.

Many examples of such reactions involve Li exchange with Sn :. The tin-lithium exchange reactions have one major advantage over the halogen-lithium exchanges for the preparation of organolithium reagents, in that the product tin compounds C 4 H 9 SnMe 3 in the example above are much less reactive towards lithium reagents than are the halide products of the corresponding halogen-lithium exchanges C 4 H 9 Br or C 4 H 9 Cl.

Other metals and metalloids which undergo such exchange reactions are organic compounds of mercury , selenium , and tellurium.

Organolithium reagents, including n -BuLi are used in synthesis of specific aldehydes and ketones. One such synthetic pathway is the reaction of an organolithium reagent with disubstituted amides :.

This process, which consumes butyllithium to generate butane, induces a reverse cycloaddition to give enolate of acetaldehyde and ethylene.

Alkyl-lithium compounds are stored under inert gas to prevent loss of activity and for reasons of safety. From Wikipedia, the free encyclopedia.

Organolithium reagent. NBL, BuLi, 1-lithiobutane. CAS Number. Interactive image. PubChem CID.

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